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            壽光市恒泰新材料有限公司

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            白炭黑與主基料顆粒粘附怎樣改善主基料流動性?

            添加時間:2019-08-23


                 通常白炭黑微粒必須能粘附在主基料顆粒的表面上,從而影響主基料顆粒的物性。這種粘附作用的程度可以是覆蓋住顆粒的全部表面,到星星點點地覆蓋住顆粒的部分表面。但不管怎樣,白炭黑顆粒和主基料顆粒之間存在親和力,它們將形成一種有序的混合物。今天小編帶著大家了解一下白炭黑產生抗結作用的機理,希望對您有所幫助。 
                (1)提供物理阻隔作用。當主基料顆粒表面被白炭黑顆粒完全覆蓋住以后,由于白炭黑之間的作用力較小,形成的白炭黑層自然成了一種阻隔主基料顆粒相互作用的物理屏障。這種物理屏障將導致幾種結果,其一是白炭黑阻隔了主基料表面的親水性物質,因吸濕或因制備時尚剩的游離水分所形成的顆粒間的液橋;其二是白炭黑吸附在主基料的表面后,使其更為光滑,從而降低了顆粒間的摩擦力,增加了顆粒的流動性,這一作用常被稱作潤滑作用。由于各種白炭黑自身性質各異,所以它們提供的潤滑作用也不同。    
                (2)通過與主基料顆粒競爭吸濕,而改善主基料的吸濕結塊傾向。一般來說,白炭黑自身具有很大的吸濕能力,從而在與主基料競爭吸濕的情況下,會減少主基料因吸濕性而導致的結塊傾向。 
                (3)通過消除主基料表面的靜電荷和分子作用力來提高其流動性。微膠囊化粉末顆粒帶有的電荷一般相同,因此,它們之間會相互排斥,防止結塊。但是這些產品上的靜電荷常會與生產裝置或包裝材料的摩擦靜電相互作用而帶來許多麻煩。當添加白炭黑后,白炭黑會中和主基料顆粒表面的電荷,從而改善主基料粉末的流動性。這種作用常用來解釋當白炭黑與主基料顆粒之間的親和力不是很大,白炭黑只是零星分散在主基料顆粒的表面時卻能很好地改善其流動性的原因。    
                (4)通過改變主基料結晶體的晶格,形成一種易碎的晶體結構。當主基料中能結晶的物質的水溶液中或已結晶的顆粒的表面上存在有白炭黑時,它不僅能抑制晶體的生長,還能改變其晶體結構,從而產生一種在外力作用下十分易碎的晶體。使原本易形成堅硬團塊的主基料的結團現象減少,改善其流動性。
             
             
             

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